In 1888, Friedrich Reinitzer (1858-1927) discovered the liquid
crystalline nature of cholesterol extracted from carrots (that is,
two melting points and generation of colors) and published his
findings at a meeting of the Vienna Chemical Society on May 3,
1888 (F. Reinitzer: Beiträge zur Kenntniss des Cholesterins,
Monatshefte für Chemie (Wien) 9, 421-441 (1888)).[1]
1904: Otto Lehmann published his work "Liquid Crystals".
1911: Charles Mauguin described the structure and properties of
liquid crystals.
1936: The Marconi Wireless Telegraph company patented the first
practical application of the technology, "The Liquid Crystal
Light Valve".
1962: The first major English language publication on the subject
"Molecular Structure and Properties of Liquid Crystals",
by Dr. George W. Gray.[2]
1962: Richard Williams of RCA found that liquid crystals had some
interesting electro-optic characteristics and he realized an
electro-optical effect by generating stripe-patterns in a thin
layer of liquid crystal material by the application of a voltage.
This effect is based on an electro-hydrodynamic instability
forming what is now called “Williams domains�?inside the liquid
crystal.[3]
1964: In the fall of 1964 George H. Heilmeier, then worked in the
RCA laboratories on the effect discovered by Williams realized the
switching of colors by field-induced realignment of dichroic dyes
in a homeotropically oriented liquid crystal. Practical problems
with this new electro-optical effect made Heilmeier to continue
work on scattering effects in liquid crystals and finally the
realization of the first operational liquid crystal display based
on what he called the dynamic scattering mode (DSM). Application
of a voltage to a DSM display switches the initially clear
transparent liquid crystal layer into a milky turbid state. DSM
displays could be operated in transmissive and in reflective mode
but they required a considerable current to flow for their
operation.
Pioneering work on liquid crystals was undertaken in the late
1960s by the UK's Royal Radar Establishment at Malvern. The team
at RRE supported ongoing work by George Gray and his team at the
University of Hull who ultimately discovered the cyanobiphenyl
liquid crystals (which had correct stability and temperature
properties for application in LCDs).
1968: NCR's John L. Janning invented liquid crystal displays
(LCD). NCR History. Retrieved on 2008-01-24.
1970: On December 4, 1970, the twisted nematic field effect in
liquid crystals was filed for patent by Hoffmann-LaRoche in
Switzerland, (Swiss patent No. 532 261) with Wolfgang Helfrich and
Martin Schadt (then working for the Central Research Laboratories)
listed as inventors.[4] Hoffmann-La Roche then licensed the
invention to the Swiss manufacturer Brown, Boveri & Cie who
produced displays for wrist watches during the 1970's and also to
Japanese electronics industry which soon produced the first
digital quartz wrist watches with TN-LCDs and numerous other
products. James Fergason at the Westinghouse Research Laboratories
in Pittsburgh while working with Sardari Arora and Alfred Saupe at
Kent State University Liquid Crystal Institute filed an identical
patent in the USA on April 22, 1971.[7] In 1971 the company of
Fergason ILIXCO (now LXD Incorporated) produced the first LCDs
based on the TN-effect, which soon superseded the poor-quality DSM
types due to improvements of lower operating voltages and lower
power consumption.
1972: The first active-matrix liquid crystal display panel was
produced in the United States by T. Peter Brody.[8]
2008: LCD TVs are the main stream with 50% market share of the 200
million TVs forecasted to ship globally in 2008. [9]
A detailed description of the origins and the complex history of
liquid crystal displays from the perspective of an insider during
the early days has been published by Joseph A. Castellano in
"Liquid Gold, The Story of Liquid Crystal Displays and the
Creation of an Industry" [10].
The same history seen from a different perspective has been
described and published by Hiroshi Kawamoto, available at the IEEE
History Center.